Anmol Chemicals is the pioneer manufacturers of Ceric Ammonium Nitrate, Ceric or Cerium Chloride or Sulfate, Pharmaceutical Excipients Food & Flavor chemicals in India. We offer Halal and Kosher Ceric Ammonium Nitrate, Ceric or Cerium Chloride or Sulfate made in an ISO9001, ISO22000 (FSSC22000) cGMP and GLP certified facility. Our group has several manufacturing facilities spread across the world, supported by toll manufacturers and representatives in UAE, Europe, USA, China and has several associated manufacturing facilities spread across India. All the Information on Physics, Chemistry, Applications, Uses and Technology on Manufacture of Ceric Ammonium Nitrate, Ceric or Cerium Chloride or Sulfate is in these pages.
The units have one or more of the certifications like FDA GMP, ISO 9001, ISO 22000, HACCP, REACH, Kosher & Halal

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Cerium Ceric Ammonium Chloride SDS GHS, MSDS Sheet

Specifications of Cerium or Ceric Chloride

Cerium Chloride SDS, Safety Data Sheet

1. Product Identification

Synonyms: Cerium chloride hydrate; Cerium Chloride (Ceric); Cerium (III) chloride; (III) chloride hydrate Cerium chloride Heptahydrate; Cerous chloride Heptahydrate; Cerium (III) chloride, hydrous; Cerium(+3) chloride Heptahydrate; Cerous chloride hydrated; Cerium (III) chloride Heptahydrate.
CAS No.: 18618-55-8 (Heptahydrate)  7790-86-5 (Anhydrous) & 19423-76-8 (Monohydrate)
EINECS EC Number: 232-227-8
Molecular Weight: 372.58 for heptahydrate; 246.48 for anhydrous
Chemical Formula: - CeCl3.7H2O for heptahydrate; CeCl3 for anhydrous
Intended Use: Industrial Manufacturing
SUPPLIER: As per Letterhead above.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3

Labeling according Regulation (EC) No 1272/2008 [CLP]

GHS Label Elements
Irritant
Irritant

Signal Word: Warning

Hazard statements:
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

Precautionary statements:
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+352: IF ON SKIN: Wash with soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P332+313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbol(s): Xi
R-phrase(s): R36/37/38 Irritating to eyes, respiratory system and skin.
S-phrase(s):
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 Wear suitable protective clothing.

OSHA Hazards: Irritant.
HMIS (Perceived): Health hazard: 2, Flammability: -, Physical hazards: -
NFPA (Perceived): Health hazard: 2, Fire: -, Reactivity Hazard: -

3. Composition/Information on Ingredients

Ingredient: Cerium Chloride Heptahydrate III
EINECS EC Number: 232-227-8
CAS No.: 18618-55-8 (Heptahydrate)
Percent: 97 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Treat symptomatically.

5. Fire Fighting Measures

Flammability of the Product: The product is not flammable.
Auto-Ignition Temperature: NA.
Products of Combustion: Hydrochloric Acid, Chlorine, Cerium oxide
Explosion: Not likely.
Fire Extinguishing Media: Use means suitable for extinguishing surrounding fire. Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information
 In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by swabbing and then spreading water on the contaminated surface and allow evacuating through the sanitary system.

7. Handling and Storage

Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Cerium Chloride in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage or contact with moisture, oxidizing material.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Not established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Cerium Chloride is white or slight yellow crystals powder or granules.
Odor: None
Solubility: Soluble in water.
pH: -- at 1% solution at 25 C (77F)
Density: 3.9 to 4 gm/cc. It varies.
Molecular Weight: 246.48 for anhydrous & 372.58 for heptahydrate
Molecular Formula: - CeCl3 for anhydrous & CeCl3.7H2O for heptahydrate
% Volatile by volume @ 21C (70F): -
Boiling Point: 1727
Melting Point: 848C

10. Stability and Reactivity

Stability: Cerium Chloride is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic fumes of Chlorine, Hydrochloric acid and Cerium oxide when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents, Acids, Moisture.
Conditions to Avoid
: Acids, Water.

11. Toxicological Information

Toxicity to Animals:
Oral, rat: LD50 > 2111 g/kg
Oral, mouse: LD50 = 5277 mg/kg
Carcinogenic Effects: Not a reported carcinogen.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

12. Ecological Information

Environmental Toxicity: Not available.
BOD5 and COD
: Not available.
Environmental Fate: No information found. Hazardous short term degradation products are not likely. However, long term degradation products may arise.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. Small amounts of this material may be suitable for sanitary sewer or trash disposal.

14. Transport Information

DOT (USA)
Not regulated.
IMDG
Not regulated.
IATA
Not regulated.

15. Regulatory Information

USA:
OSHA Hazards
: Irritant.
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
Section 313: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Acute health hazard.
TSCA: CAS# 18618-55-8 is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form is on the inventory (40CFR720.3(u)(2)).
CAS# 7790-86-5 is listed on the TSCA inventory.
Health & Safety Reporting List: None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs: None of the chemicals in this material have an RQ.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
California Prop 65: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Massachusetts Right To Know Components: Not Listed.
Pennsylvania Right To Know Components: Cerium (III) chloride heptahydrate, CAS-No.: 18618-55-8

EINECS EC Number: 232-227-8
Hazard Symbols: Xi
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face protection.
WGK (Water Danger/Protection): --

Canada - DSL/NDSL: CAS# - is listed on Canada’s DSL list.
Canadian WHMIS Classifications: D2B
CAS# - is not listed on Canada’s ingredient disclosure list.

Section 16 - Additional Information

H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
H335 = May cause respiratory irritation.
Hazard symbol(s): Xi = Irritant
R-phrase(s): R36/37/38 = Irritating to eyes, respiratory system and skin.

Disclaimer:
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Our company provides this Cerium Chloride SDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Cerium Ceric Chloride manufacturers at:

Anmol Chemicals
S-8, SARIFA MANSION, 2ND FLANK ROAD, CHINCHBUNDER, MUMBAI 400009, INDIA
TEL: (OFFICE) 91-22-23770100, 23726950, 23774610, 23723564. FAX: 91-22-23728264

e-mail: anmolc@mtnl.net.in

Anmol Chemicals

Exports to USA, Canada, UAE, Dubai, South Africa, Tanzania, Kenya, Nigeria, Egypt, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Europe Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Vietnam, Korea, Japan, etc.

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